In this paper, we propose a generalized alternating direction method of multipliers (ADMM) with semi-proximal terms for solving a class of convex composite conic optimization problems, of which some are high-dimensional, to moderate accuracy. Our primary motivation is that this method, together with properly chosen semi-proximal terms, such as those generated by the recent advance of block symmetric Gauss–Seidel technique, is capable of tackling these problems. Moreover, the proposed method, which relaxes both the primal and the dual variables in a natural way with a common relaxation factor in the interval of (0, 2), has the potential of enhancing the performance of the classic ADMM. Extensive numerical experiments on various doubly non-negative semidefinite programming problems, with or without inequality constraints, are conducted. The corresponding results showed that all these multi-block problems can be successively solved, and the advantage of using the relaxation step is apparent.